Cationic Interference in Mercury Analysis by Cold Vapour Atomic Absorption Spectroscopy

Determination of total mercury in biological tissues by flow injection cold vapour generation atomic absorption spectrometry following tetramethylammonium hydroxide digestion.

A simple, rapid and reliable method was developed for the determination of total mercury in biological samples. Samples were solubilized using tetramethylammonium hydroxide (TMAH). The organically bound mercury was cleaved and converted to inorganic mercury by on-line addition of KMnO4. The decomposed mercury together with inorganic mercury originally present in samples was determined by flow i...

Determination of total mercury in bauxite and bauxite residue by flow injection cold vapour atomic absorption spectrometry

Indirect Determination of Ascorbic Acid by Atomic Absorption Spectroscopy

A new and simple method followed by atomic absorption spectrometry has been developedfor indirect determination of ascorbic acid (AA). The proposed method was based on the oxidationof AA to dehydroascorbic acid with Cu2+cation(200mgL-1)in an ammonium thiocyanatesolution atpH2.4. AA reduces Cu2+to Cu+followed by the precipitation of Cu+ with SCN-. Then, the excess ofCu2+in the solution was measu...

Cold vapour atomic fluorescence determination of mercury in milk by slurry sampling using multicommutation

A highly sensitive mechanized method has been developed for the determination of mercury in milk by atomic fluorescence spectrometry (AFS). Samples were sonicated for 10 min in an ultrasound water bath in the presence of 8% (v/v) aqua regia, 2% (v/v) antifoam A and 1% (m/v) hydroxilamine hydrochloride, and after that, they were treated with 8 mmol l−1 KBr and 1.6 mmol l−1 KBrO3 in an hydrochlor...

Determination of mercury in rice by MSFIA and cold vapour atomic fluorescence spectrometry.

In the present paper the use of a MSFIA system for determination of mercury in rice by cold vapour atomic fluorescence spectrometry (CV AFS) is proposed. The sample digestion is performed in a microwave oven using nitric acid and hydrogen peroxide. The experimental conditions for vapour generation were determined using a full two-level factorial design involving the following factors: nitric ac...